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Milestones in Microwave Chemistry
Paperback | Engels | SpringerBriefs in Molecular Science | SpringerBriefs in Green Chemistry for Sustainability
€ 52,95
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Omschrijving
This book looks back on thirty-five years of microwave (MW) chemistry and explains how the application of the MW technique became an integral part of R&D, eventually becoming recognized in industry. Further, it details how MW chemistry has undergone a dynamic development in the past three decades, one driven by the advent of increasingly sophisticated professional MW reactors in place of the kitchen MW ovens used in earlier years. A major part of the book shows how substitutions, esterifications, amidations, hydrolyses, alkylations, eliminations, dehydrations, condensations, cyclizations, C-C couplings and the modification of heterocycles can be performed advantageously under MW irradiation, as the reaction times are shorter, while the selectivity and yields are higher; it also explains why in most cases, the reactions can be performed under solvent-free conditions. MW irradiation within the sphere of organophosphorus chemistry is showcased and typical reactions, such as the direct derivatization of phosphinic acids, alkylating esterifications, Diels-Alder reactions, the inverse Wittig-type reaction, fragmentations, the Arbuzov reaction, the synthesis of α-hydroxyphosphonates and α-aminophosphonates (the Kabachnik-Fields condensation), deoxygenations and P-C coupling reactions are described under MW conditions. In closing, the advantages of MW chemistry such as faster reactions and the possibility of simplifying the catalytic systems are addressed.
Specificaties
Betrokkenen
- Uitgeverij:
Inhoud
- Aantal bladzijden:
- 110
- Taal:
- Engels
- Reeks:
Eigenschappen
- Productcode (EAN):
- 9783319306308
- Verschijningsdatum:
- 30/03/2016
- Uitvoering:
- Paperback
- Formaat:
- Trade paperback (VS)
- Afmetingen:
- 156 mm x 234 mm
- Gewicht:
- 181 g
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